Microwave-assisted synthesis of anionic metal-organic frameworks under ionothermal conditions.
نویسندگان
چکیده
Two new isostructural coordination polymers with novel anionic metal-organic frameworks are synthesized under microwave conditions using an ionic liquid EMIm-Br as solvent and template.
منابع مشابه
Structure-directing effects of ionic liquids in the ionothermal synthesis of metal–organic frameworks
Traditional synthesis of metal-organic frameworks (MOFs) involves the reaction of a metal-containing precursor with an organic linker in an organic solvent at an elevated temperature, in what is termed a 'solvothermal' reaction. More recently, many examples have been reported of MOF synthesis in ionic liquids (ILs), rather than an organic solvent, in 'ionothermal' reactions. The high concentrat...
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عنوان ژورنال:
- Chemical communications
دوره 19 شماره
صفحات -
تاریخ انتشار 2006